Textile wet processing
Textile wet
processing is one of the major streams in textile engineering and refers to textile
chemical processing and applied science. It is usually done on the manufactured
assembly of interlacing fibers, filaments, or yarns having a substantial
surface area in relation to its thickness, and adequate mechanical strength to
give it a cohesive structure. An alternative way to say, the wet process is
done on manufactured fabric. The processes of this stream are carried out in an
aqueous stage and thus it is called a wet process which usually covers
pretreatment, dyeing, printing, and finishing. All of these stages are required an aqueous medium that is created by water. A massive amount of water is required
in these processes per day. It is estimated that, on average, almost 100-110
liter of water is used to process only 1 kg of textile goods. Water can be of
various qualities and attributes. Not all water can be used in textile
processing, it must have certain properties, quality, color, and properties for
use in textile processes. That is why water is concerned with wet processing.
Water for wet processing
Most
water used in the textile industry is from deep well water which is observed
800ft beneath the surface level. The main hassle which is concerned with the
usage of water in textile processes is water hardness resulting from the
presence of soluble salts of metals which include calcium and magnesium. Iron,
aluminum, and copper salts may also make contributions to the hardness,
however, their results are much less. Using difficult water within the wet process can motive problems consisting of the formation of scale in boilers,
reactions with soap and detergents, reactions with dyes, and issues due to Iron.
Water
hardness may be removed with the aid of the boiling procedure, liming process,
soda-lime method, Base Exchange system, or artificial ion exchange procedure.
Recently some groups have started harvesting rainwater to be used in wet
procedures as its miles are much less probably to reason the issues related to
water hardness.
Pretreatment of wet processing
Wet
processing is the most important section in textile preparation and processing.
It is a major branch of textile engineering under the Department of Textile
Chemical Processing and Applied Sciences. Textile production covers everything
from fiber to clothing; there are many variable processes that are found with
the complexity of finishing and dyeing processes in a wide range of product
production stages, including cutting, fabrication, fabric dyeing, printing,
finishing, garment, or garment production.
In
the textile industry, wet processing plays a vital role in the area of
pre-treatment, dyeing, printing, and finishing of both fabrics and apparel.
Coloration in the fiber stage or yarn stage is also included in the wet
processing division.
All
the processes of this section are carried out in an aqueous medium. The main
processes of this section are bellows-
a. Singeing
process
Singeing
is a procedure that is performed for the purpose of removing loose hairy fibers
scattered from the surface of the fabric, giving it a smooth, even, and clean
appearance. This is a necessary process for products or textile materials that
will suffer from mercerizing, dyeing, and printing to get the best results from
these processes.
In this process, first, the fabric goes over the brush to increase the fibers,
then goes over a plate heated by the flame of gas. When done on cotton fabrics,
it results in reduced durability, better dyeing properties, improved
reflection, no frosty appearance, a smoother surface, better printing
precision, improved visibility of the fabric structure, less peeling, and
reduced contamination resulting in fluff and debris removal.
Singeing
machines can be of three types: plate sizing, roller sizing, or gas sizing. Gas
singeing is broadly used in the textile industry. When the gas singeing, a
flame comes in direct contact with the fabric and burns the expanding fiber.
Here, the flame height and fabric speed are the main concerns to reduce fabric
damage.
Singeing
is done only on woven fabric. In the case of woven fabrics, however, a similar
process to singeing is known as bio-polishing where the enzyme is used to
remove protruding fibers.
b. Desizing process
It
is the process of removing sizing materials from the fabric or garments which
are applied in order to increase the strength of the yarn which can withstand
the friction of the loom. The fabric which has not been desized, it is very
stiff and causes difficulty in its treatment with a different solution in
subsequent processes.
After
the singeing operation, the sizing material is removed by making it water-soluble
and washing it with warm water. Desizing may be done by the hydrolytic method
or the oxidative method.
Depending
on the sizing materials which one has been used, the cloth may be steeped in
dilute acid and then rinsed, or enzymes may be used to break down the sizing
material. Enzymes are used in the desizing process if starch is applied as
sizing materials. Carboxymethyl cellulose (CMC) and Polyvinyl alcohol (PVA) are
often used as sizing materials.
c. Scouring process
Scouring
is a chemical washing technique that is carried out on cotton fabric to remove
natural wax and fibrous impurities from fibers and any added soil or dirt. It
is usually carried in iron containers called coir. The fabric is boiled in an
alkali, which makes soap with free fatty acids. Kier is usually closed, so a
solution of sodium hydroxide can be boiled under pressure by excluding oxygen
which reduces the cellulose of the fiber. If appropriate reagents are used, the
scoring will also remove the shape from the fabric although de-sizing is often
done before shaking and this is considered a separate process is known as
fabric preparation. Preparation and scouring are other prerequisites for other
finishing processes. At this stage even very naturally white cotton fibers are
yellow in color and bleaching, the next process is necessary. The three main
processes involved in this scouring are saponification, emulsification, and
detergency.
The
main chemical reaction used in cotton wool is sodium hydroxide which converts
saponifiable fats and oils into soaps dissolve minerals and convert pectose
and pectin to their soluble mass. Another scouring chemical is detergent that
is an emulsifying agent and removes dust and dirt particles from the fabric.
Since sodium hydroxide can cause damage to the cotton substrate. Because of
this, and to reduce the alkaline component in the flowing matter, bio-scouring
is introduced in a scouring process where biological agents are used, such as
an enzyme.
d. Bleaching process
Bleaching
is the next process of scouring, where natural color removed and textiles get
permanent white. Bleach improves whiteness by removing natural coloration and
remaining trace impurities from the cotton. The power of bleaching necessary is
determined by the required whiteness and absorbency. Cotton being a cellulose
fiber will be bleached using an oxidizing agent, such as dilute sodium
hypochlorite or dilute hydrogen peroxide. When the fabric is to be dyed a deep
shade, then lower levels of bleaching are acceptable. However, for white
bedsheets and medical applications, the highest levels of whiteness and
absorbency are essential. Reductive bleaching is also carried out, using sodium
hydrosulfite. Fibers like polyamide, polyacrylics, and polyacetates can be
bleached using reductive bleaching technology. After scouring and bleaching,
optical brightening agents (OBA), are used to make the textile material appear
whiter. These OBAs are available in different tints such as blue, violet, and
red.
e. Mercerization process
Mercerization
is a process by which cotton fabrics and threads shine like silk and strengthen
them. The process is applied to cellulosic materials such as cotton or flax.
The process is accomplished by a solution of 55–65 ° twaddle sodium hydroxide.
More likely Mercerizing is the swelling of the fibers during which the fabric
is treated with a sodium hydroxide solution. The result is improved luster,
strength, and pigmentation. Cotton is synthetic in excitation and all alkalis
must be washed off before the tension is expressed or compressed. Mercerizing
can occur directly on gray cloth or after bleaching.
f. Dyeing process
Solution dyeing
Solution dyeing is also called dope or spun dyeing, is the process of adding pigments or insoluble dyes to the spinning solution before the solution is extruded through the spinneret. Only manufactured fibers can be solution-dyed. It is used for difficult-to-dye fibers such as olefin fibers, and for dyeing fibers for end uses that require excellent colorfastness properties. Because the color pigments become a part of the fiber, solution-dyed materials have excellent colorfastness to light, washing, rubbing, perspiration, and bleach. Dyeing at the solution stage is more expensive since the equipment has to be cleaned thoroughly each time a different color is produced. Thus, the variety of colors and shades produced is limited. In addition, it is difficult to stock the inventory for each color. Decisions regarding color have to be made very early in the manufacturing process. Thus, this stage of dyeing is usually not used for apparel fabrics.Gel dyeing
Filament fibers that are produced using the wet spinning method can be dyed while the fibers are still in the coagulating bath. The dye penetration at this stage is high as the fibers are still soft. This method is known as gel dyeing.Fiber dyeing
There
are many types of dyeing is done for fiber dyeing. The names refer to the stage
at which the fiber is when it is dyed. All three are included under the broad
category of fiber dyeing.
Stock dyeing is dyeing raw
fibers, also called stock, before they are aligned, blended, and spun into
yarns.
Top dyeing is dyeing
worsted wool fibers after they have been combed to straighten and remove the
short fibers. The wool fiber at this stage is known as the top. Top dyeing is
preferred for worsted wools as the dye does not have to be wasted on the short
fibers that are removed during the combing process.
Tow dyeing is dyeing
filament fibers before they are cut into short staple fibers. The filament fibers
at this stage are known as tow.
The dye penetration is
excellent in fiber dyeing, therefore the amount of dye used to dye at this
stage is also higher. Fiber dyeing is comparatively more costly than yarn,
fabric, and product dyeing. The decision regarding the selection of colors has
to be made early in the manufacturing process. Fiber dyeing is typically used
to dye wool and other fibers that are used to produce yarns with two or more
colors. Fibers for tweeds and fabrics with a “heather” look are often fiber
dyed.
Yarn dyeing
Fabric dyeing
It is also called piece dyeing, is dyeing fabric after it has been constructed. It is economical and the most common method of dyeing solid-colored fabrics. The decision regarding color can be made after the fabric has been manufactured. Thus, it is suitable for quick response orders. Dye penetration may not be good in thicker fabrics, so yarn dyeing is sometimes used to dye thick fabrics in solid colors. Various types of dyeing machines are used for piece dyeing. The selection of the equipment is based on factors such as dye and fabric characteristics, cost, and the intended end-use.Union dyeing
It is "a method of dyeing where a fabric
containing two or more types of fibers or yarns to the same shade so as to
achieve the appearance of a solid-colored fabric". Fabrics can be dyed
using a single or multiple step process. Union dyeing is used to dye solid
colored blends and combination fabrics commonly used for apparel and home
furnishings.
Cross dyeing
Cross
dyeing is “a method of dyeing blend or combination fabrics to two or more
shades by the use of dyes with different affinities for the different
fibers”. The cross dyeing process can be used to create heather effects,
and plaid, check, or striped fabrics. Cross dyed fabrics may be mistaken for
fiber or yarn-dyed materials as the fabric is not a solid color, a
characteristic considered typical of piece-dyed fabrics. It is not possible to
visually differentiate between cross-dyed fabrics and those dyed at the fiber
or yarn stage. An example is cross dyeing blue worsted wool fabric with
polyester pinstripes. When dyed, the wool yarns are dyed blue, whereas the
polyester yarns remain white.
Cross dyeing is commonly
used with pieces of fabric dyed materials. However, the same concept is applicable
to yarn and product dyeing. For example, silk fabric embroidered with white
yarn can be embroidered prior to dyeing and product dyed when an order is
placed.Garments dyeing
Garments
dyeing is also known as product dyeing, is the process of dyeing products such
as hosiery, sweaters, and carpet after they have been produced. This stage of
dyeing is suitable when all components dye the same shade. This method is used
to dye sheer hosiery since it is knitted using tubular knitting machines and
then stitched prior to dyeing. Tufted carpets, with the exception of carpets
produced using solution-dyed fibers, are often dyed after they have been
tufted. This method is not suitable for apparel with many components such as
lining, zippers, and sewing thread, as each component may dye differently. The
exception is tinting jeans with pigments for a “vintage” look. In tinting,
color is used, whereas in other treatments such as acid-wash and stone-wash,
chemical or mechanical processes are used. After garment construction, these
products are given the "faded" or "used" look by finishing
methods as opposed to dying.
Dyeing at this stage is
ideal for a quick response. Many t-shirts, sweaters, and other types of casual
clothing are product dyed for maximum response to fashion’s demand for certain
popular colors. Thousands of garments are constructed from prepared-for-dye
fabric and then dyed to colors that sell best.Printing process
Textile printing is referred
to as localized dyeing. It is the application of color in the form of a paste
or ink to the surface of a fabric, in a predetermined pattern. Printing designs
onto already dyed fabric is also possible. In properly printed fabrics the
color is bonded with the fiber, so as to resist washing and friction. Textile
printing is related to dyeing but, whereas in dyeing proper the whole fabric is
uniformly covered with one color, in printing one or more colors are applied to
it in certain parts only, and in sharply defined patterns. In printing, wooden
blocks, stencils, engraved plates, rollers, or silkscreens can be used to place
colors on the fabric. Colorants used in printing contain dyes thickened to
prevent the color from spreading by capillary attraction beyond the limits of
the pattern or design.
Finishing process
Textile finishing is the term used for a series of processes to which all bleached, dyed, printed, and
certain grey fabrics are subjected before they put on the market. The object of
textile finishing is to render textile goods fit for their purpose or end-use
and/or improve the serviceability of the fabric.
Finishing on fabric is
carried out for both aesthetic and functional purposes to improve the quality
and look of a fabric. Fabric may receive considerable added value by applying
one or more finishing processes. Finishing processes are below-
Raising finishing
A raising card is used to raise cloth. It is the
technique used to produce the nap of cloth. Originally, only woolen cloth
was raised, but now flannelette and other cotton fabrics are also raised.
Raising is one of the last steps in the finishing process for cloth. It teases
out the ends of the fibers in the cloth to produce a nap. The raising was first
using the dried fruit pod of a teasel plant, then technology moved on and
raising cards were created. A raising card is a brush with metal bristles, similar
to hand cards, and to the original teasel pod. The process was mechanized
during the industrial revolution, and the raising machine looks and works much
like the large carding machines, in that it has a large main roller with
several small ones positioned around it. The small ones rotate quickly, in
either the same direction or opposite of that of the cloth. After the raising
process, the nap is uneven. In order to gain an even surface, the nap is then
sheared, or cut, to the desired height. There are two types of raising machine;
Teasel machine and Card-wire machine. The speed of the card-wire raising
machine varies from 12-15 yards per minute, which is 20-30% higher than that of
teasel-raising. That is why the card-wire raising machine is widely used.
Calendaring
Calendaring is a finishing
process used to smooth, coat, or thin a material. With textiles, the fabric is
passed through calender rollers at high temperatures and pressures. It is used
on fabrics such as moiré to produce its watered effect and also on cambric and
some types of sateens. In preparation for calendaring, the fabric is folded
lengthwise with the front side, or face, inside, and stitched together along
the edges. The fabric can be folded together at full width, however, this is
not done as often as it is more difficult. The fabric is then run through
rollers that polish the surface and make the fabric smoother and more lustrous.
High temperatures and pressure are used as well. Fabrics that go through the calendaring
process feel thin, glossy, and papery. The wash durability of a calendared
finish on thermoplastic fibers like polyester is higher than on cellulose
fibers such as cotton. On blended fabrics such as Polyester/Cotton, the
durability depends largely on the proportion of synthetic fiber component
present as well as the amount and type of finishing additives used and the
machinery and process conditions employed.
Crease resistance
Crease formation in woven or
knitted fabric composed of cellulose during washing or folding is the main
drawback of cotton fabrics. The molecular chains of the cotton fibers are
attached to each other by weak hydrogen bonds. During washing or folding, the
hydrogen bonds break easily, and after drying new hydrogen bonds form with the
chains in their new position and the crease is stabilized. If crosslinks between
the polymer chains can be introduced by cross-linking chemicals, then it
reinforces the cotton fibers and prevents the permanent displacement of the
polymer chains when the fibers are stressed. It is therefore much more
difficult for creases to form or for the fabric to shrink on washing.
Softening process
The fibers at the fabric surface are squashed
and frayed, and this condition hardens while drying the laundry in the air, giving
the laundry a harsh feel. Adding a liquid fabric softener to the final rinse
results in the laundry that feels softer. Fabric softeners are usually either
in the form of a liquid, which is added to the washing machine during the rinse
cycle; or as a dryer sheet which is added to the moist laundry at the beginning
of the dryer cycle. Liquid fabric softeners can be added manually during the
rinse cycle or automatically if the machine has a dispenser designed for this
purpose.
Fabric softeners coat
the surface of a fabric with chemical compounds that are electrically charged,
causing threads to "stand up" from the surface and thereby imparting
a softer and fluffier texture. Cationic softeners bind by electrostatic
attraction to the negatively charged groups on the surface of the fibers and
neutralize their charge. The long aliphatic chains then line up towards the
outside of the fiber, imparting lubricity.
Fabric softeners impart
antistatic properties to fabrics and thus prevent the build-up of electrostatic
charges on synthetic fibers, which in turn eliminates fabric cling during
handling and wearing, crackling noises, and dust attraction. Also, fabric
softeners make fabrics easier to iron and help reduce wrinkles in garments. In
addition, they reduce drying times so that energy is saved when softened
laundry is tumble-dried. Last but not least, they can also impart a pleasant
fragrance to the laundry.
Water-repellent process
Water-repellent coatings are basically just a step up from water-resistant
coatings. If a device is labeled as water-repellent it actually possesses the properties
in which to, you guessed it, repel water from it, making it hydrophobic. A water-repellent device stands a very high chance of being coated with some form of thin-film
nanotechnology, whether that is on the inside, outside, or both, and has a much
better chance of standing up to water than your average device. Many companies
claim water-repellency, but the term is heavily debated because a durable water-repellent is rare and because of all
the questions and unpredictable elements associated with it.
Fire-retardant process
Fire-retardant
fabrics are textiles that are more resistant to fire than others through
chemical treatment or manufactured fireproof fibers. The term fire-retardant as
applied to organic (i.e., containing carbon) materials, is intended to refer to
reduced fire hazard, as all will burn under certain circumstances. The tests
used specified in building codes, such as NFPA 701, are more correctly flame
resistance tests, which test a fabric's ability to resist ignition with the
flame size and duration in the test conditions.
When
a fabric is designated as inherently fire-retardant, permanently
fire-retardant, or durably fire-retardant, the flame retardancy will last for
the life of the fabric as it has been woven into the fabric fiber itself. The
drapery can be laundered or dry-cleaned as recommended by the drapery
manufacturer. In the case of fabrics that are designated as fire-retardants
that have been topically treated with chemicals the flame retardancy of the
fabric will dissipate over time, particularly with repeated cleaning. As these
chemicals are soluble in liquids-either water or dry cleaning fluid, these
fabrics must be dry-cleaned with a non-liquid cleaning agent. The flame
retardants work by coating the flammable fabrics with a mineral-based barrier, preventing
a fire from reaching the fibers.
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